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From Wiki.cyring.fr

pacman -S xfce4

startxfce

chromium --user-data-dir=/tmp/

.config/xfce4/xfconf/xfce-perchannel-xml/

xfce4-desktop.xml

<?xml version="1.0" encoding="UTF-8"?>

<channel name="xfce4-desktop" version="1.0">

 <property name="backdrop" type="empty">
   <property name="screen0" type="empty">
     <property name="monitor0" type="empty">
       <property name="image-path" type="string" value="/usr/share/backgrounds/xfce/xfce-blue.jpg"/>
       <property name="last-image" type="string" value="/usr/share/backgrounds/xfce/xfce-blue.jpg"/>
       <property name="last-single-image" type="string" value="/usr/share/backgrounds/xfce/xfce-blue.jpg"/>
     </property>
   </property>
 </property>
 <property name="desktop-icons" type="empty">
   <property name="icon-size" type="uint" value="32"/>
   <property name="file-icons" type="empty">
     <property name="show-home" type="bool" value="false"/>
     <property name="show-filesystem" type="bool" value="false"/>
     <property name="show-trash" type="bool" value="false"/>
   </property>
 </property>

</channel>

xfce4-panel.xml
<?xml version="1.0" encoding="UTF-8"?>

<channel name="xfce4-panel" version="1.0">

 <property name="configver" type="int" value="2"/>
 <property name="panels" type="array">
   <value type="int" value="1"/>
   <property name="panel-1" type="empty">
     <property name="position" type="string" value="p=6;x=17;y=72"/>
     <property name="mode" type="uint" value="1"/>
     <property name="size" type="uint" value="48"/>
     <property name="background-style" type="uint" value="1"/>
     <property name="plugin-ids" type="array">
       <value type="int" value="4"/>
       <value type="int" value="3"/>
       <value type="int" value="1"/>
     </property>
     <property name="position-locked" type="bool" value="true"/>
     <property name="length" type="uint" value="100"/>
     <property name="background-color" type="array">
       <value type="uint" value="23589"/>
       <value type="uint" value="37012"/>
       <value type="uint" value="45286"/>
       <value type="uint" value="65535"/>
     </property>
   </property>
 </property>
 <property name="plugins" type="empty">
   <property name="plugin-1" type="string" value="tasklist">
     <property name="show-labels" type="bool" value="false"/>
     <property name="show-handle" type="bool" value="false"/>
   </property>
   <property name="plugin-3" type="string" value="systray"/>
   <property name="plugin-4" type="string" value="clock">
     <property name="mode" type="uint" value="4"/>
     <property name="show-frame" type="bool" value="false"/>
   </property>
 </property>

</channel>